Premium
Oligomeric carbon and siloxane series observed by matrix‐assisted laser desorption/ionisation and laser desorption/ionisation mass spectrometry during the analysis of soot formed in fuel‐rich flames
Author(s) -
Apicella Barbara,
Ciajolo Anna,
Millan Marcos,
Galmes Carolina,
Herod Alan A.,
Kandiyoti Rafael
Publication year - 2004
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1337
Subject(s) - chemistry , desorption , siloxane , mass spectrometry , soot , analytical chemistry (journal) , mass spectrum , silicone oil , carbon fibers , dichloromethane , organic chemistry , chromatography , polymer , materials science , composite material , solvent , adsorption , composite number , combustion
Oligomeric carbon and siloxane series have been observed by matrix‐assisted laser desorption/ionisation mass spectrometry (MALDI‐MS), during the analysis of the dichloromethane (DCM)‐soluble fractions of condensable material recovered from fuel‐rich flames. Laser desorption (LD) spectra showed a pattern of oligomeric dimethyl‐siloxane structures with a spacing of 74 u. The siloxane series appears to have originated as contamination of samples by silicone oil used to lubricate connections of polymer tubing. This was confirmed by extracting silicone tubing and silicone grease with DCM followed by MALDI‐MS analysis. A series of peaks with a mass spacing of 24 u was also observed, superimposed on the continuum of unresolved organic ions. This oligomeric series appears to correspond to polycyclic aromatics separated by (mainly) ethylene bridges. Thus LD‐MS appears to have revealed a series of soot precursors, intermediate between polycyclic aromatics and particulate soot, which was not detected by MALDI‐MS. More detailed work is necessary to define these species with precision. Copyright © 2004 John Wiley & Sons, Ltd.