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Mass spectrometric study of some zirconocene and hafnocene diadamantanolates
Author(s) -
Grafov Andrei V.,
Koval Ludmila I.,
Traldi Pietro,
Catinella Silvia,
Battiston Giovanni A.,
Zanella Pierino
Publication year - 1995
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290090915
Subject(s) - chemistry , fragmentation (computing) , mass spectrometry , electron ionization , kinetic energy , ionization , metallocene , ion , analytical chemistry (journal) , metal , organic chemistry , chromatography , polymerization , physics , polymer , quantum mechanics , computer science , operating system
The electron ionization mass spectrometric behaviour of a new series of hafnocene and zirconocene diadamantanolates is discussed. They are also compared on the basis of mass‐analyzed ion kinetic energy spectrometry. Fragmentation patterns of the complexes in question give relevant information on their gas‐phase behaviour as MO 2 /MC (M = Zr, Hf) precursors for metal‐organic chemical vapour deposition.