Premium
Electron ionization mass spectrometry of 2‐halo ethanols
Author(s) -
Carbini Massimo,
Napoli Massimo,
Gambaretto Giampaolo,
Traldi Pietro
Publication year - 1995
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290090112
Subject(s) - chemistry , electronegativity , mass spectrometry , metastability , deuterium , electron ionization , halogen , chemical ionization , ion , ionization , electron , analytical chemistry (journal) , computational chemistry , organic chemistry , atomic physics , nuclear physics , chromatography , physics , alkyl
The mass spectrometric behaviour of 2‐fluoro, 2‐chloro, 2‐bromo and 2‐iodo ethanols has been studied in detail with the aid of metastable ion studies and deuterium labelling experiments. Clear differences are observed and rationalized in terms both of carbon–halogen bond strengths and electronegativity.