Formation of pentavalent silicon anions, (CH 3 O) 2 Si(OEt)       3    −     and CH 3 OSiH(OEt)       3    −    , in the gas phase | Zendy

Murthy Vemisetty S. | Zendy; Miller Jack M. | Zendy

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Formation of pentavalent silicon anions, (CH 3 O) 2 Si(OEt) 3 − and CH 3 OSiH(OEt) 3 − , in the gas phase

Author(s) -

Murthy Vemisetty S.,

Miller Jack M.

Publication year - 1994

Publication title -

rapid communications in mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.528

H-Index - 136

eISSN - 1097-0231

pISSN - 0951-4198

DOI - 10.1002/rcm.1290080907

Subject(s) - chemistry , gas phase , dissociation (chemistry) , medicinal chemistry , silicon , hydride , argon , ligand (biochemistry) , inorganic chemistry , organic chemistry , metal , receptor , biochemistry

We describe the formation of pentavalent silicon anions, (CH 3 O) 2 Si(OEt) 3 −and CH 3 OSiH(OEt) 3 − , by a ligand exchange and a hydride reaction in the presence of argon buffer in the gas phase. A simple elimination is followed by double and triple cyclic elimination mechanisms, during the collision‐induced dissociation of CH 3 OSiH(OEt) 3 − .

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