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Gas‐phase rearrangements involving homoenolate anions. The isocamphanone/camphor rearrangement
Author(s) -
Eichinger Peter C. H.,
Bowie John H.
Publication year - 1994
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290080308
Subject(s) - chemistry , camphor , deprotonation , gas phase , ion , organic chemistry
Deprotonated isocamphanones rearrange to deprotonated camphor in the gas phase, presumably via the intermediacy of a homoenolate anion.