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Stereospecific Retro‐Diels‐Alder reactions in the negative‐ion mass spectra of Diels‐Alder adducts of substituted p ‐benzoquinones and glucofuranodienes
Author(s) -
Madhusudanan K. P.,
Dhami T. S.,
Rani A.,
Suryawanshi S. N.
Publication year - 1993
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290070119
Subject(s) - chemistry , stereospecificity , adduct , diels–alder reaction , mass spectrum , medicinal chemistry , ion , alder , stereochemistry , organic chemistry , catalysis , botany , biology
The negative ions of cis ‐ and trans ‐Diels‐Alder adducts of p‐benzoquinones and glucofuranodienes enable these stereoisomers to be differentiated because the cis ‐ isomers undergo a highly‐favoured retro‐Diels‐Alder reaction.
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