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Mass spectrometric studies on some macrocyclic, macrobicyclic and macroacyclic Schiff bases
Author(s) -
Guerriero P.,
Tamburini S.,
Vigato P. A.,
Catinella S.,
Traldi P.
Publication year - 1992
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290061206
Subject(s) - chemistry , mass spectrometry , condensation , amine gas treating , kinetic energy , fast atom bombardment , ion , tris , schiff base , polymer chemistry , organic chemistry , chromatography , thermodynamics , biochemistry , physics , quantum mechanics
The mass spectrometric behaviour of four macrocyclic, one macrobicyclic and one macroacyclic Schiff bases, obtained by one‐step multiple condensation reactions of 2,6‐diformyl‐4‐methylpropane, 1,3‐diamino‐ 2,2‐dimethylpropene, 1,5‐diamino‐3‐oxapentane or tris‐(2‐aminoethyl) amine under fast‐atom bombardment conditions, was studied in detail with the aid of mass‐analyzed ion kinetic energy spectrometry. The mass spectrometric behaviour of a mononuclear macrobicy La(III) complex is also described.