The chemistry of transition‐metal ion interactions with cyclohexylamine in the gas phase | Zendy

Chen LinZhi | Zendy; Miller Jack M. | Zendy

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The chemistry of transition‐metal ion interactions with cyclohexylamine in the gas phase

Author(s) -

Chen LinZhi,

Miller Jack M.

Publication year - 1992

Publication title -

rapid communications in mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.528

H-Index - 136

eISSN - 1097-0231

pISSN - 0951-4198

DOI - 10.1002/rcm.1290060803

Subject(s) - chemistry , cyclohexylamine , ion , transition metal , aniline , inorganic chemistry , molecule , benzene , metal , fast atom bombardment , qualitative inorganic analysis , metastability , photochemistry , organic chemistry , catalysis

The formation of transition‐metal ion (M + Fe + , CO + , Ni + and Mn + ) complexes with cyclohexylamine (1) in a modified fast‐atom bombardment (FAB) source, and the reactions of various ion/molecule complexes, have been studied by FAB MASS spectrometry combined with metastable ion and collisional activation techniques. Multiples dehydrogenations to produce [(aniline)·M] + and consecutive [2H 2 +NH 3 ] elimination to afford [(benzene)·M] + from 1 prevail for all the metal ions studied. Furthermore, [(1)·][Ni] + and [(1) 2 ·Co] + ions underwent an unusual NH 3 loss. Relative reactivities of the metal ions and complicated ligand effects are presented.

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