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Observation of the fullerene anions C 60 − and C 70 − by electrospray ionization
Author(s) -
Hiraoka Kenzo,
Kudaka Ichiro,
Fujimaki Susumu,
Shinohara Hisanori
Publication year - 1992
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290060406
Subject(s) - chemistry , electrospray ionization , dimethoxyethane , fullerene , ionization , ion , benzene , solvent , analytical chemistry (journal) , chromatography , organic chemistry , electrode , electrolyte
Abstract Mass spectsrometric investigation on the fullerence C 60 and C 70 was performed using electsdrospray ionization. C 60 − , C 60 O 2 − , C 70 − , and C 70 O 2 −ions were detected by reducing C 60 and C 70 using Nak amalgam in benzene + dimethoxyethane solvent. C 70 −was found to be much more reactive than C 60 −in solution.