Observation of the fullerene anions C       60    −     and C       70    −     by electrospray ionization | Zendy

Hiraoka Kenzo | Zendy; Kudaka Ichiro | Zendy; Fujimaki Susumu | Zendy; Shinohara Hisanori | Zendy

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Observation of the fullerene anions C 60 − and C 70 − by electrospray ionization

Author(s) -

Hiraoka Kenzo,

Kudaka Ichiro,

Fujimaki Susumu,

Shinohara Hisanori

Publication year - 1992

Publication title -

rapid communications in mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.528

H-Index - 136

eISSN - 1097-0231

pISSN - 0951-4198

DOI - 10.1002/rcm.1290060406

Subject(s) - chemistry , electrospray ionization , dimethoxyethane , fullerene , ionization , ion , benzene , solvent , analytical chemistry (journal) , chromatography , organic chemistry , electrode , electrolyte

Mass spectsrometric investigation on the fullerence C 60 and C 70 was performed using electsdrospray ionization. C 60 − , C 60 O 2 − , C 70 − , and C 70 O 2 −ions were detected by reducing C 60 and C 70 using Nak amalgam in benzene + dimethoxyethane solvent. C 70 −was found to be much more reactive than C 60 −in solution.

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