Structure interconversion in isomeric guanine derivatives at elevated sample temperature | Zendy

Kralj B. | Zendy; Kramer V. | Zendy; Žigon D. | Zendy; Kobe J. | Zendy; Plavec J. | Zendy

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Structure interconversion in isomeric guanine derivatives at elevated sample temperature

Author(s) -

Kralj B.,

Kramer V.,

Žigon D.,

Kobe J.,

Plavec J.

Publication year - 1992

Publication title -

rapid communications in mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.528

H-Index - 136

eISSN - 1097-0231

pISSN - 0951-4198

DOI - 10.1002/rcm.1290060113

Subject(s) - chemistry , guanine , ion , decomposition , tandem , tandem mass spectrometry , mass spectrometry , computational chemistry , mass spectrum , analytical chemistry (journal) , chromatography , organic chemistry , biochemistry , nucleotide , materials science , composite material , gene

Guanine derivatives were examined using the tandem mass spectrometry (MS/MS) method. Isomeric structure differences were explored by means of the unimolecular decomposition spectra of the common ion m/z 151 having the empirical formula of the guanine molecular ion. An interconversion of the isomeric structures as the sample temperature is gradually raised, was observed.

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