Fast‐atom bombardment mass spectrometry and metastable‐ion studies for the characterization of isomeric fluorosugars | Zendy

Kiremire B. T. | Zendy; Chirello D. | Zendy; Traldi P. | Zendy; Bravo P. | Zendy; Resnati G. | Zendy

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Fast‐atom bombardment mass spectrometry and metastable‐ion studies for the characterization of isomeric fluorosugars

Author(s) -

Kiremire B. T.,

Chirello D.,

Traldi P.,

Bravo P.,

Resnati G.

Publication year - 1991

Publication title -

rapid communications in mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.528

H-Index - 136

eISSN - 1097-0231

pISSN - 0951-4198

DOI - 10.1002/rcm.1290051205

Subject(s) - chemistry , fast atom bombardment , ion , metastability , mass spectrometry , ionic bonding , characterization (materials science) , atom (system on chip) , mass spectrum , analytical chemistry (journal) , chromatography , organic chemistry , nanotechnology , materials science , computer science , embedded system

Characterization of stereoisomeric 3,4‐dideoxy‐3‐fluoro‐hexoses has been carried out using fast‐atom bombard‐ment. Diagnostic fragments were observed in the daughter‐ion spectra of the [M‐H] − and [M+H] + ionic species. Notable differences were also observed in the relataivae abundances of ionic species corresponding to [M‐H] − , [M‐H‐HF] − and [C 11 H 11 O 2 ] − ions.

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