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Specific reactivity of the ‘magic bullet’ matrix in the negative‐ion fast‐atom bombardment mass spectra of organic anions
Author(s) -
Aubagnac JeanLouis,
Man Michel Wong Chi,
Elguero José
Publication year - 1991
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290051009
Subject(s) - chemistry , reactivity (psychology) , magic bullet , fast atom bombardment , mass spectrum , ion , mass spectrometry , boron , matrix (chemical analysis) , silicate , organic chemistry , medicine , bioinformatics , alternative medicine , pathology , chromatography , biology
The magic bullet matrix shows a noticeable and specific reactivity towards two organometallic anions (borate and silicate). Thus, before selecting this matrix to study organic salts by fast‐atom bombardment mass spectrometry, it is necessary to check for this specific reactivity.