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Behaviour of tetrabutylammonium tribromide under fast‐atom bombardment using protic and aprotic matrices
Author(s) -
Lange C.,
Benammar Y.,
Berthelot J.
Publication year - 1991
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290050809
Subject(s) - chemistry , tribromide , ion , atom (system on chip) , matrix (chemical analysis) , inorganic chemistry , organic chemistry , chromatography , computer science , embedded system
Tetrabutylammonium tribromide in a protic matrix, under FAB desorptiono, does not provide the tribromide anion as it does in the gas phase. In contrast, using an aprotic matrix it gives a complex tribromide anion.