Gas‐phase chemistry of metal oxide anions. The reactions of dioxomanganate(III), MnO       2    −     and trioxomanganate(V), MnO       3    −     ions with aliphatic alcohols | Zendy

Fokkens R. H. | Zendy; Gregor I. K. | Zendy; Nibbering N. M. M. | Zendy

Premium

Gas‐phase chemistry of metal oxide anions. The reactions of dioxomanganate(III), MnO 2 − and trioxomanganate(V), MnO 3 − ions with aliphatic alcohols

Author(s) -

Fokkens R. H.,

Gregor I. K.,

Nibbering N. M. M.

Publication year - 1991

Publication title -

rapid communications in mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.528

H-Index - 136

eISSN - 1097-0231

pISSN - 0951-4198

DOI - 10.1002/rcm.1290050808

Subject(s) - chemistry , hydride , inorganic chemistry , ion , qualitative inorganic analysis , metal , oxide , alcohol , metal ions in aqueous solution , medicinal chemistry , organic chemistry

Results of gas‐phase reactions of MnO 2 −and MnO 3 −ions with a series of aliphatic C 1 C 4 alcohols show that C 2 C 4 primary alcohols are oxidized by MnO 2 −in reaction channels which involve proton abstraction and hydride‐ion transfer, along with the appearance of [H.Mn.O.OH] − ions. Secondary alcohols are oxidized in slower processes while menthanol and t‐butanol are unreactive. MnO 3 − /alcohol reactions are more complex and involve the formation of [H.MnO 3 ] − , [H.Mn.O 2 .OH] − , [RO.Mn.O.OH] − , [(RO) 2 Mn.O] − and the terminal solvated ion [(RO) 3 .Mn.OH] − .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research