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A facile method for the localization of a double bond in aliphatic compounds
Author(s) -
Schneider B.,
Budzikiewicz H.
Publication year - 1990
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290041217
Subject(s) - chemistry , chemical ionization , mass spectrometry , microscale chemistry , ionization , double bond , desorption , gas chromatography , chromatography , gas chromatography–mass spectrometry , flame ionization detector , organic chemistry , ion , adsorption , mathematics education , mathematics
Olefinic aliphatic compounds can be transformed on a microscale into the corresponding epoxides by reaction with m ‐chloroperbenzoic acid. The crude reaction mixture can be analysed without further work‐up, by gas chromatography followed by chemical ionization mass spectrometry or desorption chemical ionization mass spectrometry with nitric oxide as the chemical ionization gas.