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A fourier transform‐ion cyclotron resonance study of the reactivity of ionized vinylalcohol with selected unsaturated compounds
Author(s) -
Berruyer Florence,
Bouchoux Guy
Publication year - 1990
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290041105
Subject(s) - chemistry , fourier transform ion cyclotron resonance , reactivity (psychology) , thermochemistry , mass spectrometry , ion , proton , ion cyclotron resonance , fourier transform , benzene , ionization , resonance (particle physics) , analytical chemistry (journal) , inorganic chemistry , cyclotron , organic chemistry , atomic physics , nuclear physics , chromatography , mathematical analysis , physics , alternative medicine , mathematics , pathology , medicine
Reactions between CX 2 CXOX +· (X H or D) and alkenes, an alkyne, benzene, aldehydes and ketones have been studied by Fourier transform mass spectrometry. Most of the neutral species undergo charge exchange or proton transfer reactions with high rates; l‐alkenes lead to slower cycloaddition reactions. The thermochemistry and considerations on the reaction specificities are discussed.