Loss of H 2  from metastable CH 3 SiH       2    +     ions | Zendy

Tobita Seiji | Zendy; Nakajima Katsuyoshi | Zendy; Tajima Susumu | Zendy; Shigihara Atsushi | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Loss of H 2 from metastable CH 3 SiH 2 + ions

Author(s) -

Tobita Seiji,

Nakajima Katsuyoshi,

Tajima Susumu,

Shigihara Atsushi

Publication year - 1990

Publication title -

rapid communications in mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.528

H-Index - 136

eISSN - 1097-0231

pISSN - 0951-4198

DOI - 10.1002/rcm.1290041104

Subject(s) - chemistry , metastability , fragmentation (computing) , ion , kinetic energy , deuterium , dissociation (chemistry) , mndo , mass spectrometry , mass spectrum , bond dissociation energy , collision induced dissociation , analytical chemistry (journal) , atomic physics , tandem mass spectrometry , molecule , organic chemistry , physics , quantum mechanics , chromatography , computer science , operating system

Unimolecular dissociations of metastable methylsilyl cations CH 3 SiH 3 + are investigated by mass‐analysed ion kinetic energy (MIKE) spectrometry. The predominant fragmentation is H 2 loss which proceeds via at least two distinct mechanisms with substantially different kinetic energy releases. Their reaction mechanisms are inferred from the results of experiments and MNDO calculations. The MIKE spectrum of the deuterium‐labelled ion, CH 3 SiD 2 + indicates that the H and D atoms are randomized before dissociation.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research