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Fluorine influence in the mass spectrometric patterns in β‐hydroxy alkyl aryl sulphoxides. Part 5
Author(s) -
Seraglia R.,
Traldi P.,
Bravo P.,
Resnati G.,
Bortolini O.,
Cavicchio G.
Publication year - 1990
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290041006
Subject(s) - chemistry , fragmentation (computing) , halogen , alkyl , electron ionization , aryl , mass spectrometry , mass spectrum , kinetic energy , ionization , chemical ionization , ion , analytical chemistry (journal) , computational chemistry , organic chemistry , chromatography , physics , quantum mechanics , computer science , operating system
The electron ionization mass spectrometry of some β‐hydroxy alkyl aryl sulphoxides halogenated in the γ‐position is described and the mechanism of the common fragmentation patterns are discussed with the aid of linked scans at constant B/E, mass‐analysed ion kinetic energy spectra and labelling experiments. The influence of the presence of halogens is also discussed.