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The loss of amine from low internal energy ions of aminosteroid stereoisomers
Author(s) -
Mollova Nevena,
Longevialle Pierre,
Bouchoux Guy
Publication year - 1990
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290040508
Subject(s) - chemistry , amine gas treating , ion , ionization , atom (system on chip) , hydrogen , labelling , hydrogen atom , inorganic chemistry , organic chemistry , biochemistry , alkyl , computer science , embedded system
D‐labelling experiments show that the extent of hydrogen‐atom exchanges accompanying the loss of amine from ionized aminosteroids of low internal energy depends on structure and also, in a few cases, on the configuration of the amine function. Mechanisms are proposed.
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