Premium
Fourier transform ion cyclotron resonance study of the gas‐phase reaction of the yttrium ion with silane
Author(s) -
Decouzon M.,
Gal JF.,
Géribaldi S.,
Rouillard M.,
Sturla JM.,
Bouchoux G.
Publication year - 1989
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290030907
Subject(s) - fourier transform ion cyclotron resonance , chemistry , ion , ion cyclotron resonance , mass spectrometry , yttrium , dissociation (chemistry) , silane , analytical chemistry (journal) , fragmentation (computing) , cyclotron resonance , fourier transform , atomic physics , cyclotron , chromatography , physics , organic chemistry , quantum mechanics , computer science , operating system , oxide
Abstract Preliminary results obtained with a home‐made Fourier transform ion cyclotron resonance mass spectrometer on the sequential clustering reactions of silane using yttrium cation activation are reported. [YSi n H 2n ] + and [YSi n H 2n − 2 ] + ions are formed. So far, we have observed these ions up to n = 7 , and a sequential clustering mechanism is proposed. The ion structures are characterized by collision‐induced dissociation, and kinetic measurements to determine the formation and decay rates of each ion are performed.