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Tandem mass spectrometry of fatty acid methyl esters. Evidence for bicyclic product ions
Author(s) -
Cairns Thomas,
Siegmund Emil G.
Publication year - 1989
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290030506
Subject(s) - chemistry , homologous series , protonation , bicyclic molecule , mass spectrometry , tandem mass spectrometry , ion , hydride , molecule , mass spectrum , tandem , medicinal chemistry , stereochemistry , organic chemistry , chromatography , materials science , composite material , hydrogen
Product‐ion spectra derived from both protonated and hydride‐abstracted molecules of long chain esters have revealed an unusual homologous series of ions which suggest a cyclization mechanism to form stabilized bicyclodecenes or bicyclononenes.
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