How are S       2    +·     ions formed in electron collisions with linear SCS? | Zendy

Mazumdar S. | Zendy; Kumar S. V. K. | Zendy; Marathe V. R. | Zendy; Mathur D. | Zendy

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How are S 2 +· ions formed in electron collisions with linear SCS?

Author(s) -

Mazumdar S.,

Kumar S. V. K.,

Marathe V. R.,

Mathur D.

Publication year - 1989

Publication title -

rapid communications in mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.528

H-Index - 136

eISSN - 1097-0231

pISSN - 0951-4198

DOI - 10.1002/rcm.1290030204

Subject(s) - chemistry , ion , atomic physics , ab initio , ionization , electron , ionization energy , molecular orbital , electron ionization , field desorption , energetics , electron affinity (data page) , molecule , physics , organic chemistry , quantum mechanics , thermodynamics

The energetics of S 2 +·ion formation in electron dissociative ionization of linear CS 2 are investigated experimentally with a crossed‐beam apparatus. Ab initio self‐consistent‐field molecular orbital (SCF MO) calculations of potential energy curves for low‐lying electronic states of this ion have been made in order to explain how stable S 2 +·ions are formed, initially at the very large internuclear separation of 3.2 Å.

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