Identification of C 4 H 9 O +  isomers by collisional activation mass spectrometry | Zendy

Maquestiau André | Zendy; Beugnies Didier | Zendy; Flammang Robert | Zendy; Houriet Raymond | Zendy; Bouchoux Guy | Zendy

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Identification of C 4 H 9 O + isomers by collisional activation mass spectrometry

Author(s) -

Maquestiau André,

Beugnies Didier,

Flammang Robert,

Houriet Raymond,

Bouchoux Guy

Publication year - 1988

Publication title -

rapid communications in mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.528

H-Index - 136

eISSN - 1097-0231

pISSN - 0951-4198

DOI - 10.1002/rcm.1290020903

Subject(s) - chemistry , chloromethane , mass spectrometry , reagent , mass spectrum , ion , analytical chemistry (journal) , protonation , methane , medicinal chemistry , organic chemistry , chromatography , catalysis

C 4 H 9 O + ions have been produced in the high pressure ion source of a triple sector mass spectrometer either by protonation of C 4 H 8 O isomers using methane as the reagent gas, or by methylation of C 3 H 6 O isomers using iodomethane or chloromethane as reagent gas. The collisional activation spectra of these mass selected C 4 H 9 O + ions ( m/z 73) allow the identification of several stable isomers in the gas phase.

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