Gas‐phase ligation of Cr +  and Fe +  with 4,9‐diazapyrene | Zendy

Kazazić Saša | Zendy; Klasinc Leo | Zendy; Kovač Branka | Zendy; Srzić Dunja | Zendy

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Gas‐phase ligation of Cr + and Fe + with 4,9‐diazapyrene

Author(s) -

Kazazić Saša,

Klasinc Leo,

Kovač Branka,

Srzić Dunja

Publication year - 2003

Publication title -

rapid communications in mass spectrometry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.528

H-Index - 136

eISSN - 1097-0231

pISSN - 0951-4198

DOI - 10.1002/rcm.1204

Subject(s) - chemistry , nitrogen , mass spectrometry , gas phase , phase (matter) , pyrene , analytical chemistry (journal) , nuclear chemistry , radiochemistry , medicinal chemistry , chromatography , organic chemistry

The ligation of Cr + and Fe + with 4,9‐diazapyrene (DAP) within a Fourier transform mass spectrometer was studied and compared with previous results for the ligands pyrene (Py) and 9‐azaphenanthrene (Ap). The results confirm that Fe + , which reacts more slowly but in the same way as Cr + to bind two Py ligands, behaves quite differently with the nitrogen heterocycles DAP and Ap: it reacts rapidly and it binds three and four of them, respectively. Copyright © 2003 John Wiley & Sons, Ltd.

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