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Mass spectrometric studies of cyclopentanol derivatives in the reductive coupling of α , β ‐unsaturated ketones assisted by samarium diiodide
Author(s) -
Le Lagadec Ronan,
Rubio Laura,
Velasco Luis,
PérezFlores Javier,
Miranda Rene,
Cabrera Armando
Publication year - 2003
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1108
Subject(s) - chemistry , deuterium , samarium diiodide , samarium , molecule , computational chemistry , analytical chemistry (journal) , medicinal chemistry , organic chemistry , atomic physics , physics
The mass spectrometric fragmentations of a series of cyclopentanol derivatives in positive fast‐atom bombardment (FAB + ) mode were investigated. The corresponding pathways proposed were confirmed by MS/MS data obtained using linked scans at constant B/E, high‐resolution accurate mass data, and comparisons with corresponding information for a specifically deuterated molecule. Copyright © 2003 John Wiley & Sons, Ltd.