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Quantum defect orbital study of electron transitions in rydberg molecules. I. Triatomic hydrogen
Author(s) -
Martin I.,
Karwowski J.,
Diercksen G. H. F.,
Lavin C.
Publication year - 1993
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560480864
Subject(s) - triatomic molecule , rydberg formula , quantum defect , atomic physics , electron , rydberg atom , quantum , physics , rydberg constant , molecule , hydrogen molecule , chemistry , quantum mechanics , ion , ionization
Results of a pilot study on the applicability of the quantum defect orbital method for describing electronic transitions between molecular Rydberg states are reported. Oscillator strengths and Einstein emission coefficients for the triatomic hydrogen molecule have been calculated. The results are in good agreement with the data derived from more sophisticated theoretical approaches. © 1993 John Wiley & Sons, Inc.