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Proposed experiments for the detection of coherent–dissipative structures around H + ions in aqueous solutions
Author(s) -
ChatzidimitriouDreismann C. A.
Publication year - 2009
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560360819
Subject(s) - aqueous solution , dissipative system , ion , proton , work (physics) , chemical physics , physics , chemistry , thermodynamics , materials science , quantum mechanics
Some experimental consequences of recent work of Brändas and C.‐Dreismann on the H + transport mechanism in aqueous solutions are considered. Further analysis of the excess conductivities of H + and OH − confirms a previously established relation on proton transfer activation energies in water. Three new experiments are proposed and shortly discussed, which can show explicitly the existence of coherent‐dissipative structures around H + (or OH − ) in aqueous solutions.