z-logo
Premium
Some comments on the method of complex scaling to find physical resonance states
Author(s) -
Löwdin PerOlov
Publication year - 1986
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560300763
Subject(s) - eigenfunction , eigenvalues and eigenvectors , scaling , hamiltonian (control theory) , hilbert space , operator (biology) , complex plane , spectrum (functional analysis) , mathematics , connection (principal bundle) , mathematical analysis , pure mathematics , mathematical physics , physics , quantum mechanics , geometry , mathematical optimization , biochemistry , chemistry , repressor , transcription factor , gene
Some basic features of the method of complex scaling are briefly reviewed. This method is associated with a similarity transformation H = UHU −1 , in which the many‐particle Hamiltonian H loses its self‐adjoint character. In connection with the eigenvalue problems for H and H, one has formally the relations ψ = Uψ and E = E. However, since the proper boundary conditions have to be satisfied, the spectrum { E } may still be subject to change: even if some eigenvalues are persistent ( E = E), others may be lost, and new eigenvalues may occur also in the complex plane. It is pointed out that these changes are related to the fact that the “dilatation operator” U is an unbounded operator, and that the eigenfunctions involved are transformed not only within the ordinary L 2 Hilbert space, but also out of and into this space. Reference to a more complete treatment is given.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here
Accelerating Research

Address

John Eccles House
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom