Effect of electron correlation on the forced electric‐dipole transition probabilities in  f N   systems. III. Some aspects of the mechanism of hypersensitive transitions | Zendy

SmentekMielczarek L. | Zendy; Jankowski K. | Zendy

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Effect of electron correlation on the forced electric‐dipole transition probabilities in f N systems. III. Some aspects of the mechanism of hypersensitive transitions

Author(s) -

SmentekMielczarek L.,

Jankowski K.

Publication year - 2009

Publication title -

international journal of quantum chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.484

H-Index - 105

eISSN - 1097-461X

pISSN - 0020-7608

DOI - 10.1002/qua.560240838

Subject(s) - electronic correlation , dipole , electron , atomic physics , electric dipole transition , physics , correlation , atomic electron transition , magnetic dipole , nuclear physics , quantum mechanics , mathematics , geometry , spectral line

The results of model studies of the impact of electron correlation on the forced electric‐dipole transition probabilities between the levels of the f N configuration in rare‐earth systems are presented. The method of this investigation, developed by the present authors, has a different tensorial structure than the commonly used Judd–Ofelt theory. The detailed analysis of the corrections due to the electron correlation for several regular and hypersensitive transitions in Pr +3 and Eu +3 doped in LaCl 3 is performed.

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