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Effect of electron correlation on the forced electric‐dipole transition probabilities in f N systems. III. Some aspects of the mechanism of hypersensitive transitions
Author(s) -
SmentekMielczarek L.,
Jankowski K.
Publication year - 2009
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560240838
Subject(s) - electronic correlation , dipole , electron , atomic physics , electric dipole transition , physics , correlation , atomic electron transition , magnetic dipole , nuclear physics , quantum mechanics , mathematics , geometry , spectral line
The results of model studies of the impact of electron correlation on the forced electric‐dipole transition probabilities between the levels of the f N configuration in rare‐earth systems are presented. The method of this investigation, developed by the present authors, has a different tensorial structure than the commonly used Judd–Ofelt theory. The detailed analysis of the corrections due to the electron correlation for several regular and hypersensitive transitions in Pr +3 and Eu +3 doped in LaCl 3 is performed.