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Application of the unitary group approach to crystal field theory
Author(s) -
Zhenyi Wen
Publication year - 1983
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560230323
Subject(s) - unitary state , group (periodic table) , unitary group , symmetry (geometry) , field (mathematics) , octahedron , group theory , symmetry group , crystal (programming language) , crystal field theory , octahedral symmetry , theoretical physics , computational chemistry , mathematics , physics , chemistry , quantum mechanics , crystallography , pure mathematics , crystal structure , geometry , computer science , law , ion , political science , programming language
An analytical treatment for a strong crystal field in an octahedral symmetry by using the unitary group approach is given. It shows that the convenience of the unitary group approach is comparable with that of the Racah method.