Perturbation for a rigid rotator in an electric field | Zendy

Requena A. | Zendy; Peña R. | Zendy; Serna A. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Perturbation for a rigid rotator in an electric field

Author(s) -

Requena A.,

Peña R.,

Serna A.

Publication year - 1982

Publication title -

international journal of quantum chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.484

H-Index - 105

eISSN - 1097-461X

pISSN - 0020-7608

DOI - 10.1002/qua.560220609

Subject(s) - rigid rotor , perturbation (astronomy) , wave function , eigenvalues and eigenvectors , stark effect , electric field , physics , perturbation theory (quantum mechanics) , quantum electrodynamics , quantum mechanics , classical mechanics , rotor (electric) , atomic physics

The behavior of a rigid rotor perturbed by an electric field is studied. An hypervirial calculation, to obtain the perturbation series without calculation of the perturbed wavefunctions, is used to determine the Stark‐shifted eigenvalues. A numerical estimation of the m equals; 0 → m = 1 transition for the lowest vibrational state ( v = 0) and the first rotational state ( J = 1) for the HF and DF molecules using Padé approximants is made.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research