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Infrared absorption of nonpolar molecules in rattling motion
Author(s) -
Hirokawa Shoji
Publication year - 1980
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560180225
Subject(s) - homonuclear molecule , van der waals force , diatomic molecule , molecule , radius , chemistry , van der waals strain , infrared , absorption (acoustics) , heteronuclear molecule , van der waals radius , molecular physics , physics , atomic physics , quantum mechanics , optics , computer security , computer science
Abstract A theoretical study has been made on the translational or “rattling” motion of homonuclear diatomic molecules encaged in β‐quinol clathrates. By the use of an adjustable parameter for the van der Waals radius, experimental results have been explained fairly well.