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Production of new compounds by vibrational dissociation
Author(s) -
Bak Børge,
Svanholt Henrik
Publication year - 2009
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560120831
Subject(s) - dissociation (chemistry) , photodissociation , excitation , ultraviolet , chemistry , microwave , photochemistry , chemical physics , atomic physics , computational chemistry , materials science , physics , optoelectronics , quantum mechanics
It is suggested that chemical species heated to several hundred degrees at a pressure of 0.001‐0.100 mm Hg undergo dissociation as a result of “pure” vibrational excitation without those effects associated with photolysis (visible‐ultraviolet), microwave discharges, etc. Aspects of a future theoretical treatment are discussed.