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The spin‐orbit interaction in the configuration nl N n ' l using nonorthogonal radial orbitals
Author(s) -
Jucys A. P.,
Sabas K. V.,
Kupliauskis Z. J.
Publication year - 1975
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560090415
Subject(s) - atomic orbital , configuration interaction , atomic physics , excited state , physics , orbit (dynamics) , spin (aerodynamics) , electron configuration , spin–orbit interaction , slater type orbital , operator (biology) , chemistry , linear combination of atomic orbitals , quantum mechanics , ion , electron , biochemistry , repressor , gene , transcription factor , engineering , thermodynamics , aerospace engineering
Formulas for the calculation of matrix elements of the simplified operator of the spin‐orbit interaction for the configuration n 1 l N n 2 l are deduced for the case when radial orbitals are nonorthogonal. The coefficients of the radial integrals are tabulated for the configuration p N p . The fine structure of the excited configuration of the carbon atom is calculated.