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The “seniority” classification of spin hamiltonian and states of complexes and molecules in approximation of one‐centered plethysms
Author(s) -
Men B. A.,
Leschinsky M. L.,
Men A. N.
Publication year - 1975
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560090409
Subject(s) - seniority , hamiltonian (control theory) , molecule , spin (aerodynamics) , impurity , physics , quantum mechanics , chemistry , mathematical physics , atomic physics , mathematics , thermodynamics , mathematical optimization , political science , law
A modification of the concept of “seniority” for the classification of the permitted terms and the effective operators in complexes and molecules is presented. Tables of the states of complexes of impurity orbital nondegenerate ions ( N = 3, 4) with spin S ( \documentclass{article}\pagestyle{empty}\begin{document}$ S = \frac{1}{2} - \frac{7}{2} $\end{document} ) and the corresponding tensorial operators are given.