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Calculation of the magneto–optical activity of the hydrogen molecule
Author(s) -
Svendsen E. Nørby,
Hameka Hendrik F.
Publication year - 1974
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560080514
Subject(s) - verdet constant , molecule , constant (computer programming) , faraday effect , hydrogen , atomic physics , atmosphere (unit) , rotation (mathematics) , hydrogen molecule , magneto optical , physics , chemistry , magnetic field , quantum mechanics , thermodynamics , geometry , mathematics , computer science , programming language
We calculated the Verdet constant of the hydrogen molecule. We found that the angle of rotation may be represented by ϕ 0 = A 0 Hv 2 /( v 0 2− v 2 ) 2 where A 0 is 3.23 × 10 −33 microminutes sec 2 per oersted‐cm‐atmosphere. This is in agreement with the experimental observations where ϕ 0 is given by the same frequency dependence with the constant A 0 × 2.72 = 10 −33 in terms of the same units.
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