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Spin‐spin splitting factors for f 7 electron configurations
Author(s) -
Saxena K. M. S.,
Malli Gulzari
Publication year - 2009
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560050870
Subject(s) - spin (aerodynamics) , perturbation (astronomy) , wave function , perturbation theory (quantum mechanics) , electron , zero field splitting , atomic physics , condensed matter physics , physics , chemistry , spin polarization , quantum mechanics , thermodynamics
Expressions of the spin‐spin splitting factors ( p ) for all the terms of f 7 electron configuration are evaluated and tabulated for general usage in the first‐order perturbation calculations. The values of the splitting factors for Eu(4 f 7 ), Eu ++ (4 f 7 ), and Gd +++ (4 f 7 ) obtained utilizing the above mentioned expressions and Hartree‐Fock wave functions are also presented.