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Polarization contribution to the dipole moment and infrared spectrum intensity of the benzene–iodine complex
Author(s) -
Mantione MarieJosé
Publication year - 1969
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560030204
Subject(s) - dipole , infrared , halogen , benzene , polarization (electrochemistry) , chemistry , ground state , iodine , atomic physics , infrared spectroscopy , bond dipole moment , moment (physics) , molecular physics , transition dipole moment , physics , optics , quantum mechanics , organic chemistry , alkyl
Polarization is shown to play a non‐negligible role in two properties of the ground state of benzene–iodine type complexes: their dipole moment, and the halogen infrared spectrum. These results, compared with preceding results concerning π–π complexes, suggest that the ground‐state properties of charge‐transfer complexes should not be interpreted exclusively by the usual resonance mode.