Premium
Quadrupole antishielding factors for ions and atomic states
Author(s) -
Sternheimer R. M.
Publication year - 2009
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.560010607
Subject(s) - ion , quadrupole , atomic physics , chemistry , electromagnetic shielding , ionic bonding , physics , quantum mechanics , organic chemistry
A general discussion of the shielding and antishielding effects of nuclear quadrupole moments for ions and atomic states is presented. Values of the ionic antishielding factor γ∞ have been obtained for the following ions: Y 3+ , In 3+ , Bi 3+ , and Am 2+ . The hexa‐decapole antishielding factor ∞ has been evaluated for the case of In 3+ . The general properties of the atomic correction factor R are also discussed. Values of R have been calculated for several atomic states, and were found to be in reasonable agreement with experiment.