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Does the gradient‐regulated connection improve the description of correlated metal bond properties?
Author(s) -
Mostafa Rola,
Brémond Éric,
Adamo Carlo,
Ciofini Ilaria,
Morell Christophe,
Chermette Henry
Publication year - 2019
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.25831
Subject(s) - density functional theory , covalent bond , connection (principal bundle) , bond energy , metal , bond dissociation energy , chemistry , materials science , chemical physics , computational chemistry , dissociation (chemistry) , statistical physics , molecular physics , molecule , physics , quantum mechanics , mathematics , geometry , organic chemistry
Gradient‐regulated connection (GRAC) is a generalized gradient approximation exchange density functional designed by combining the revPBE and PW91 exchange functionals to impose their behaviors in the slowly‐ and fast‐varying density regions, respectively. Such a construction allows one single density functional to accurately estimate both covalent and weak interactions occurring in main‐group‐based molecular systems. For the first time, the assessment of the performance of the GRAC exchange functional is extended to the modeling of various metal bond energy and structure properties. This assessment shows that when GRAC is coupled with the Perdew, Burke, Ernzerhof (PBE) correlation, the resulting exchange‐correlation density functional is an excellent alternative to global hybrids to model bond dissociation energy, atomic electronic excitation energy, and bond length structure properties of single‐reference metal bonds. It also shows that coupling with the Tognetti, Cortona, Adamo (TCA) correlation constitutes a robust approach to tackle energy bond properties of organometallic complexes with multi‐reference character.