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Quantum‐matter photonic framework perspective of chemical processes: Entanglement shifts in HCN/CNH isomerization
Author(s) -
Tapia Orlando
Publication year - 2015
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.24962
Subject(s) - isomerization , photonics , quantum entanglement , quantum , basis (linear algebra) , photon , quantum mechanics , physics , base (topology) , chemistry , mathematics , biochemistry , geometry , catalysis , mathematical analysis
A complete electro‐nuclear (EN) basis set and quantum electrodynamics bases in photon number scheme combines to form photonic bases sets. The EN q ‐states can hence be modulated by appropriate external electromagnetic sources. Quantum determinants for HCN/CNH isomerization within photonic bases are elaborated that rationalize quantum state changes as if it were an apparent unimolecular process. Topologic label of base states permit linking with those obtained with semiclassic schemes. A comparison of results leads to conclude that both schemes can turn out to be complementary. The q ‐scheme yielding more detailed information that the semiclassic one as expected. © 2015 Wiley Periodicals, Inc.