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Carbon‐donated hydrogen bonding: Electrostatics, frequency shifts, directionality, and bifurcation
Author(s) -
Compaan Katherine,
Vergenz Robert,
Von Rague Schleyer Paul,
Arreguin Isis
Publication year - 2008
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.21811
Subject(s) - hydrogen bond , chemistry , electrostatics , hydrogen , ab initio , quantum chemistry , computational chemistry , torsion (gastropod) , chemical physics , atomic physics , crystallography , molecule , supramolecular chemistry , physics , crystal structure , organic chemistry , medicine , surgery
Structure, energies, electrostatics, and vibrational modes were calculated ab initio for dimethyl sulfoxide (DMSO) and its 1:1 hydrogen bonded complex with chloride ion at the MP2/6‐311+G** level. The interaction energy is −71.476 kJ/mole. On average, the CH stretching frequencies decreased by 35 cm −1 , whereas their intensities increased by a factor of 19. Methyl torsion frequencies increased by 50–80 cm −1 . We review the past and present understanding of hydrogen bonding, and apply these perspectives to analyze properties of the complex. The stretching shifts conform to the established spectral criteria for hydrogen bonding. The bifurcated geometry of the complex and its electrostatic character are fully consistent with trends observed in classically defined hydrogen bonds. All of the established definitions and criteria for identifying hydrogen bonding have been challenged. By any of the most well‐established criteria, the DMSO/Cl − complex is hydrogen bonded. We propose a generally applicable working definition of hydrogen bonding to clarify and unify understanding of this interaction. © 2008 Wiley Periodicals, Inc. Int J Quantum Chem, 2008