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Semiempirical and spectroscopic study of a novel porphyrin dyad
Author(s) -
Janvier P.,
Le Questel J.Y.,
Illien B.,
Suresh S.,
Blart E.,
Quintard J.P.,
Odobel F.
Publication year - 2001
Publication title -
international journal of quantum chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.484
H-Index - 105
eISSN - 1097-461X
pISSN - 0020-7608
DOI - 10.1002/qua.1329
Subject(s) - dyad , porphyrin , ultraviolet , chemistry , non covalent interactions , electronic structure , computational chemistry , quantum , chemical physics , photochemistry , physics , quantum mechanics , molecule , organic chemistry , hydrogen bond , acoustics
Semiempirical calculations and ultraviolet–visible experiments have been carried out on a novel bisporphyrin system. The present work reveals that an oligothiophene ethynyl‐linked spacer promotes high electronic interactions over a large distance in this dyad. © 2001 John Wiley & Sons, Inc. Int J Quantum Chem 84: 259–263, 2001