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Formation of Few‐ and Monolayered WS 2 Sheets Using Plasma‐Treated Dimethyl‐Sulfoxide Solvent‐Based Exfoliation
Author(s) -
Esfandiari Mehrnaz,
Kamaei Sadegh,
Rajabali Mona,
Mohajerzadeh Shams
Publication year - 2020
Publication title -
physica status solidi (rrl) – rapid research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.786
H-Index - 68
eISSN - 1862-6270
pISSN - 1862-6254
DOI - 10.1002/pssr.201900396
Subject(s) - exfoliation joint , tungsten disulfide , dimethyl sulfoxide , materials science , chemical engineering , solvent , raman spectroscopy , van der waals force , molecule , nanotechnology , analytical chemistry (journal) , chemistry , graphene , organic chemistry , composite material , optics , physics , engineering
Tungsten disulfide is an emerging 2D material with unique electrical and optical properties. Although chemical vapor deposition and mechanical exfoliation lead to large‐area layers, sonication solvent‐based exfoliation is a convenient method to realize mono‐ and few‐layer flakes. Herein, a mixture of dimethyl‐sulfoxide (DMSO) and water as a safe, facile, and user‐friendly exfoliation solvent for the synthesis of large‐scale WS 2 sheets is investigated. While water molecules weaken the Van der Waals force between the stacked layers, DMSO molecules facilitate the exfoliation process. To improve exfoliation and achieve large‐area sheets, plasma pretreatment is exploited on bulk WS 2 prior to the exfoliation process. For this purpose, O 2 and H 2 gases are used to carry out the plasma pretreatment. The oxygen plasma treatment is shown to be an effective strategy, leading to large‐area features. Moreover, inert gases as He and Ar are used to obtain small sheets. Transmission electron microscopy, atomic force microscopy, Raman spectroscopy, and dynamic light scattering analyses are used to understand the mechanism of exfoliation and study the effects of various parameters as water temperature, plasma power, and duration.