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Post‐Annealing Effect on Resistive Switching Performance of a Ta/Mn 2 O 3 /Pt/Ti Stacked Device
Author(s) -
Yang Min Kyu,
Kim Gun Hwan
Publication year - 2018
Publication title -
physica status solidi (rrl) – rapid research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.786
H-Index - 68
eISSN - 1862-6270
pISSN - 1862-6254
DOI - 10.1002/pssr.201800031
Subject(s) - annealing (glass) , materials science , manganese , electrode , oxide , stoichiometry , optoelectronics , analytical chemistry (journal) , composite material , metallurgy , chemistry , organic chemistry , chromatography
A comparative study of Ta/Mn 2 O 3 /Pt/Ti stacked capacitor‐like resistive switching (RS) devices was performed as a function of the post‐annealing process conditions. Compared to as‐fabricated RS devices, the post‐annealed ones showed higher switching endurance (≈10 9 RS cycles), good retention characteristics, and narrow operational voltage distribution. To elucidate the microscopic origins of the superior RS performance, various analyses are conducted; and it is revealed that structural and chemical composition changes in post‐annealed RS devices can improve the RS performance. In the case of post‐annealed samples, unintentionally diffused Ti is observed between the manganese oxide layer and the Pt bottom electrode. Because of the metallic property of diffused Ti, it can be a good electron donor and a center of RS during the formation of a conducting filament (CF) in manganese oxide for nearly uniform RS operation. The highly reliable endurance characteristic is attributed to a TaO x layer between the Ta top electrode and the manganese oxide. The non‐stoichiometric TaO x layer that is formed during the post‐annealing process can play the role of an effective oxygen reservoir, and ≈10 4 times more RS endurance cycles could be achieved compared to the as‐fabricated RS device.