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Heteroepitaxy of Highly Oriented GaN Films on Non‐Single Crystal Substrates Using a Si(111) Template Layer Formed by Aluminum‐Induced Crystallization
Author(s) -
Hainey Mel F.,
Al Balushi Zakaria Y.,
Wang Ke,
Martin Nathan C.,
Bansal Anushka,
Chubarov Mikhail,
Redwing Joan M.
Publication year - 2018
Publication title -
physica status solidi (rrl) – rapid research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.786
H-Index - 68
eISSN - 1862-6270
pISSN - 1862-6254
DOI - 10.1002/pssr.201700392
Subject(s) - materials science , epitaxy , crystallite , crystallization , amorphous solid , chemical vapor deposition , optoelectronics , metalorganic vapour phase epitaxy , layer (electronics) , crystallography , nanotechnology , chemical engineering , metallurgy , chemistry , engineering
Growth of epitaxial III‐nitride (AlGaInN) films has long been confined to single crystal substrates which are crystallographically compatible with the hexagonal GaN (0001) surface. However, for lighting, display, and power electronics applications, growth on amorphous substrates such as fused quartz glass or on polycrystalline diamond is desirable. Several approaches to produce c‐plane oriented, textured GaN films on glass have been previously demonstrated, but are process‐intensive and limited in scalability. In this report, we demonstrate the heteroepitaxial growth of textured GaN films on fused quartz and other substrates using thin silicon film templates fabricated by aluminum‐induced crystallization (AIC). The AIC‐Si films have a uniform (>95%) Si (111) oriented surface, enabling well‐developed GaN‐on‐Si epitaxial growth processes to be adapted to new substrates. GaN films grown on fused quartz using metalorganic chemical vapor deposition (MOCVD) have uniformly c‐axis oriented grains, ≈40–50 μm in size, with random in‐plane orientations similar to those of the underlying AIC‐Si template layer. Threading dislocation densities of 8.5 ± 1.8 × 10 9 cm −2 within regions bounded by grain boundaries are comparable to GaN films grown on single crystal Si (111) substrates. Finally, highly oriented GaN growth on AIC‐Si is also achieved on both oxidized Si (001) substrates and polycrystalline diamond, demonstrating the general applicability of this approach.