Stability of sol–gel derived glass coated Eu complex using deuterated methanol | Zendy

Fukuda Takeshi | Zendy; Yamauchi Shuhei | Zendy; Honda Zentaro | Zendy; Kamata Norihiko | Zendy; Kijima Naoto | Zendy

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Stability of sol–gel derived glass coated Eu complex using deuterated methanol

Author(s) -

Fukuda Takeshi,

Yamauchi Shuhei,

Honda Zentaro,

Kamata Norihiko,

Kijima Naoto

Publication year - 2009

Publication title -

physica status solidi (rrl) – rapid research letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.786

H-Index - 68

eISSN - 1862-6270

pISSN - 1862-6254

DOI - 10.1002/pssr.200903223

Subject(s) - methanol , deuterium , thermal stability , sol gel , silica gel , ethanol , chemical engineering , oxygen , chemistry , materials science , organic chemistry , nanotechnology , physics , quantum mechanics , engineering

A high‐stability Eu complex has been achieved by coating with a silica glass via a low temperature sol–gel process using deuterated methanol. A three‐dimensional glass network protects the Eu complex from free oxygen and/or water to change the ligand structure. In addition, the chemical bond of the deuterated Eu complex is more stable than that of the conventional Eu complex. Therefore, we achieved a high‐thermal‐stability Eu complex encapsulated by a sol–gel derived silica glass using deuterated methanol instead of ethanol.(© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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