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Pentagonal ZnO nanorods
Author(s) -
Könenkamp R.,
Word R. C.,
Dosmailov M.,
Nadarajah A.
Publication year - 2007
Publication title -
physica status solidi (rrl) – rapid research letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.786
H-Index - 68
eISSN - 1862-6270
pISSN - 1862-6254
DOI - 10.1002/pssr.200701011
Subject(s) - nanorod , hexagonal crystal system , materials science , substrate (aquarium) , morphology (biology) , template , nanotechnology , deposition (geology) , chemical engineering , crystallography , chemistry , paleontology , oceanography , sediment , geology , biology , engineering , genetics
We report the growth of ZnO nanorods with pentagonal cross‐section in electrodeposition on p‐type Si substrates. Cathodic potentials smaller than those used for growth of hexagonal nanorods are used. The pentagonal wires have a typical length of 1–2 µm and grow out of an inhomogeneous nano‐crystalline thin film. We tentatively explain the occurrence of the pentagonal morphology in terms of kinetic limitations for electron transport in the p‐Si substrate and changed chemical conditions at the growth surface. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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