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Temperature Dependence of Nuclear Magnetic Resonance and Transferred Hyperfine Field of 133 Cs in a CsMnCl 3 Single Crystal
Author(s) -
Lim A. R.,
Choh S. H.,
Jeong S. Y.
Publication year - 1996
Publication title -
physica status solidi (b)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.51
H-Index - 109
eISSN - 1521-3951
pISSN - 0370-1972
DOI - 10.1002/pssb.2221980231
Subject(s) - hyperfine structure , quadrupole , chemistry , ion , single crystal , hyperfine coupling , crystal (programming language) , resonance (particle physics) , nuclear magnetic resonance , nuclear quadrupole resonance , atomic physics , paramagnetism , analytical chemistry (journal) , crystallography , condensed matter physics , physics , organic chemistry , computer science , programming language , chromatography
The nuclear magnetic resonance of 133 Cs in a CsMnCl 3 single crystal grown by the Czochralski method has been investigated by employing a Bruker FT NMR spectrometer. The resonance lines of two different Cs(I) and Cs(II) were recorded. The quadrupole coupling constants of Cs(I) and Cs(II) in CsMnCl 3 decrease as the temperature increases. The temperature dependence of e 2 qQ / h is explained with a single torsional frequency of the Cs‐Cl ion by means of the simple Bayer theory. Also, we have investigated the transferred hyperfine interaction due to the transfer of spin density from the Mn 2+ ion to the Cs + ion in the CsMnCl 3 single crystal using the magnetic susceptibility and the paramagnetic shift using nuclear magnetic resonance.