A Mössbauer Effect Investigation of Fe Hyperfine Fields and Solubility Limit of Cr in Fe 3− x   Cr  x  Si Alloys | Zendy

Babu T. V. S. M. Mohan | Zendy; Bansal C. | Zendy

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A Mössbauer Effect Investigation of Fe Hyperfine Fields and Solubility Limit of Cr in Fe 3− x Cr x Si Alloys

Author(s) -

Babu T. V. S. M. Mohan,

Bansal C.

Publication year - 1993

Publication title -

physica status solidi (b)

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.51

H-Index - 109

eISSN - 1521-3951

pISSN - 0370-1972

DOI - 10.1002/pssb.2221800219

Subject(s) - hyperfine structure , solubility , mössbauer spectroscopy , mössbauer effect , precipitation , solid solution , analytical chemistry (journal) , materials science , magnetic moment , chemistry , crystallography , metallurgy , condensed matter physics , physics , atomic physics , chromatography , meteorology

Detailed Mössbauer effect studies on Fe 3− x Cr x Si alloys show a solubility of Cr up to a composition of x = 0.5 and a precipitation of Cr 3 Si phase beyond this composition. The effect of Cr on the hyperfine fields at the inequivalent (AC) and (B) sites is understood in terms of a local environment model with Cr substituting at the B site with a very small moment. Presence of B32 order besides the DO 3 order is also indicated.

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